Article Sidebar

Submitted
Jan 5, 2023
Accepted
Jun 19, 2023
Published
Sep 30, 2023
Download
pdf
Statistic
Read Counter : 1649 Download : 91

Downloads

Download data is not yet available.

Main Article Content

Abstract

Methanol extract of Melastoma malabathricum (MEMML) contains secondary metabolites such as phenolics and flavonoids. These compounds have OH groups that can interact with Fe contained in steel and form a thin layer for corrosion inhibition on mild steel. Inhibition of mild steel corrosion using MEMML leaves in sulfuric acid solution was carried out using weight loss and potentiodynamic polarization methods. The results showed that the mild steel corrosion rate decreased and inhibition efficiency increased with the addition of MEMML. FTIR and SEM analysis showed the interaction between mild steel with MEMML forming a layer on the surface of the steel so that it inhibits corrosion. The inhibition efficiency has increased with the length of immersion time and concentration of MML methanol extract. The highest inhibition efficiency, 98.86%, was obtained at 72 hours of immersion time and 10 g / L MEMML.

Keywords

Inhibitor, corrosion, melastoma malabathricum, inhibition, extract

Article Details

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite
1.
Gusti DR, Lestari I, Farid F, Wahyudi A, Azril, Sukor MZ. Methanol Extract of Melastoma malabathricum Leaves as Eco-Friendly Corrosion Inhibitor for Mild Steel in Sulfuric Acid . EKSAKTA [Internet]. 2023Sep.30 [cited 2024Nov.23];23(03):352-61. Available from: https://eksakta.ppj.unp.ac.id/index.php/eksakta/article/view/386

References

  1. Verma, E. E. Ebenso, and M. A. Quraishi. (2017). Ionic liquids as green and sustainable corrosion inhibitors for metals and alloys: An overview, J. Mol. Liq., vol. 233,pp. 403–414.
  2. D. . Gusti, I. Lestari, F. Farid, and P. T. Sirait. (2019). Protection of mild steel from corrosion using methanol extract of avocado ( Persea americana mill ) seeds in a solution of sulfuric acid Protection of mild steel from corrosion using methanol extract of avocado (Persea americana mill) seeds in a solutio, IOP Conf. Ser. J. Phys. Conf. Ser., vol. 1282, no. 1, p. 12083.
  3. R. T. Loto. (2018). Surface coverage and corrosion inhibition effect of Rosmarinus officinalis and zinc oxide on the electrochemical performance of low carbon steel in dilute acid solutions, Results Phys., vol. 8, pp. 172–179.
  4. Q. Wang et al. (2019). Evaluation of Ficus tikoua leaves extract as an eco-friendly corrosion inhibitor for carbon steel in HCl media, Bioelectrochemistry, vol. 128, pp. 49–55.
  5. D. R. Gusti, Emriadi, A. Alif, and M. Efdi. (2016). Surface characteristics on mild steel using aqueous extract of cassava (Manihot esculenta) leaves as a corrosion inhibitor, Der Pharma Chem., vol. 8, no. 17.
  6. D. R. Gusti, E. Emriadi, and M. Efdi. (2022). Thermodynamic and Adsorption Properties of Flavonoid Rutin from Cassava (Manihot esculenta) Leaves as a Corrosion Inhibitor on the Mild Steel in Sulfuric Acid Solution, Defect Diffus. Forum, vol. 416, pp. 183–190
  7. Y. Liu et al. (2019). Effect of ginger extract as green inhibitor on chloride-induced corrosion of carbon steel in simulated concrete pore solutions, J. Clean. Prod., vol. 214, pp. 298–307.
  8. W. J. Zheng et al. (2021). A review of the traditional uses, phytochemistry and biological activities of the Melastoma genus, J. Ethnopharmacol., vol. 264, no. July 2020, p. 113322.
  9. D. M. O. Serna and J. H. I. Martínez. (2015). Phenolics and polyphenolics from melastomataceae species, Molecules, vol. 20, no. 10, pp. 17818–17847.
  10. da Silva, V. B., Almeida-Bezerra, J. W., Costa, A. R., Morais-Braga, M. F. B., de Oliveira, M. G., Pinheiro, A. A. V., ... & Costa, J. G. M. D. (2022). The Genus Miconia Ruiz & Pav.(Melastomataceae): Ethnomedicinal Uses, Pharmacology, and Phytochemistry. Molecules, 27(13), 4132.
  11. N. B. Iroha and M. N. Jane. (2020). Stem extract of Dissotis theifolia (Melastomataceae) as a green corrosion inhibitor for N80 steel in 1 M HCl solution, vol. 13, no. 3, pp. 30–38.
  12. Bomfim, E. M. S., Coelho, A. A. O. P., Silva, M. C., Marques, E. J., & Vale, V. L. C. (2021). Phytochemical composition and biological activities of extracts from ten species of the family Melastomataceae Juss. Brazilian Journal of Biology, 82.
  13. D. Kurniawan and E. Ginting. (2019). Variasi Konsentrasi Inhibitor Ekstrak Buah Harendong (Melastoma Affine D . Don) Pada Baja Per Daun Dengan Perlakuan Panas 300 Dan 700 ° C Terhadap Laju Korosi Dalam Larutan Nacl 3 %, vol. 7, no. 2, pp. 187–196.
  14. Ocampo Serna, D. M., & Isaza Martínez, J. H. (2015). Phenolics and polyphenolics from melastomataceae species. Molecules, 20(10), 17818-17847.
  15. N. Ferdous, M. Rahman, and A. Alamgir. (2018). Secondary Metabolites and Bioactivities of Melastoma Malabathricum (L.) Smith: An Anti-Diarrheal Plant of Bangladesh, To Chem. J., vol. 1, no. 3.
  16. da Silva, A. V. F., dos Santos, R. H. S., de Morais, B. A., de Araújo, M. I. F., de Souza Barbosa, P. P., de Oliveira Borba, E. F., ... & Leite, T. C. C. (2022). Phytochemical analysis and biological activity from Clidemia capitellata leaves (melastomataceae). Revista Brasileira Multidisciplinar, 25(3), 62-72.
  17. D. R. Gusti, I. Lestari, E. Permana, and R. Anggraini. (2020). Exploration o Coffee Bean Husks Waste as an Eco-Environmentally Friendly Corrosion Inhibitor on Mild Steel in Sulphuric Acis Solution, IOP Conf. Ser. Earth Environ. Sci., vol. 483, no. 1.
  18. Y. Yetri and N. Jamarun. (2015). Corrosion inhibition of environmental friendly inhibitor using Theobroma cacao peels extract on mild steel in NaCl solution, Journal of Chemical and Pharmaceutical Research, vol. 7, no. 5, pp. 1083–1094.
  19. Yetri, Y., Gunawarman, E., & Jamarun, N. (2018). Theobroma cacao peel extract as the eco-friendly corrosion inhibitor for mild steel. Corrosion inhibitors, principles and recent applications, 201-224.
  20. D. R. Gusti, Emriadi, A. Alif, and M. Efdi. (2017).Corrosion Inhibition of Ethanol Extract of Cassava ( Manihot esculenta ) Leaves on Mild Steel in Sulfuric Acid, Int. J. ChemTech Res., vol. 10, no. 2, pp. 163–171.
  21. Y. Sangeetha, S. Meenakshi, and C. S. Sundaram. (2016). Interactions at the mild steel acid solution interface in the presence of O-fumaryl-chitosan: Electrochemical and surface studies, Carbohydr. Polym., vol. 136, pp. 38–45.
  22. Li, X., Deng, S., & Fu, H. (2012). Inhibition of the corrosion of steel in HCl, H2SO4 solutions by bamboo leaf extract. Corrosion Science, 62, 163-175.
  23. Lou, Y., Chang, W., Cui, T., Wang, J., Qian, H., Ma, L., ... & Zhang, D. (2021). Microbiologically influenced corrosion inhibition mechanisms in corrosion protection: A review. Bioelectrochemistry, 141, 107883.
  24. M. V. Fiori-Bimbi, P. E. Alvarez, H. Vaca, and C. A. Gervasi. (2015). Corrosion inhibition of mild steel in HCL solution by pectin, Corros. Sci., vol. 92, pp. 192–199.
  25. Wang, X., Chen, L., Yang, F., Xiang, Q., & Liu, J. (2023). Corrosion inhibition mechanism and extraction technology of plant corrosion inhibitors: a review. Journal of Adhesion Science and Technology, 1-25.
  26. H. Li et al. (2016). Investigation of microbiologically influenced corrosion of high nitrogen nickel-free stainless steel by Pseudomonas aeruginosa, Corros. Sci., vol. 111, pp. 811–821.
  27. Javaherdashti, R., & Javaherdashti, R. (2017). Microbiologically influenced corrosion (MIC) (pp. 29-79). Springer International Publishing.
  28. F. Gapsari, S. Hidayatullah, P. Hadi Setyarini, K. A. Madurani, and H. Hermawan. (2022). Effectiveness of a fish scales-derived chitosan coating for corrosion protection of carbon steel, Egypt. J. Pet., vol. 31, no. 1, pp. 25–31.
  29. Moschona, A., Plesu, N., Mezei, G., Thomas, A. G., & Demadis, K. D. (2018). Corrosion protection of carbon steel by tetraphosphonates of systematically different molecular size. Corrosion Science, 145, 135-150.
  30. P. B. Raja, A. K. Qureshi, A. Abdul Rahim, H. Osman, and K. Awang. (2013). Neolamarckia cadamba alkaloids as eco-friendly corrosion inhibitors for mild steel in 1M HCl media, Corros. Sci., vol. 69, pp. 292–301.
  31. Chigondo, M., & Chigondo, F. (2016). Recent natural corrosion inhibitors for mild steel: an overview. Journal of Chemistry, 2016.
  32. G. A. Benabdallah et al. (2023). Eco-friendly Pistacia lentiscus leaves extract corrosion inhibitor for C38 steel in 1 M HCl, Int. J. Corros. Scale Inhib, vol. 12, no. 1, pp. 292–308.

Most read articles by the same author(s)