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Submitted
Oct 7, 2024
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Oct 30, 2024
Published
Nov 8, 2024
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Abstract

Kaolinite, a naturally abundant clay mineral, possesses a significant surface area and catalytic properties. To enhance its catalytic efficiency, modification into kaolinite nanotubes is necessary, as this transformation increases surface area and porosity. The synthesis of kaolinite nanotubes was achieved through a solvothermal method, incorporating multiple intercalation and rolling processes influenced by ultrasonic waves, subsequently utilizing these nanotubes as heterogeneous catalysts. The resulting kaolinite nanotube catalysts exhibited well-defined nanotube morphology and were applied in the transesterification of waste cooking oil, with variations in methanol-to-oil ratios. The optimal biodiesel yield achieved was 49.84%, obtained after a 3-hour reaction period using a 3% w catalyst at 60 °C, with a methanol-oil ratio of 3:1. This research highlights the potential of kaolinite nanotubes as effective catalysts in biodiesel production.

Keywords

Catalyst kaolinite nanotube transesterification waste cooking oil biodiesel

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How to Cite
1.
Muhammad Rizki, Fitri E, Syukri Arief, Rahadian Zainul, Syukri. Synthesis of Kaolinite Nanotubes as Heterogeneous Catalysts for Transesterification Reaction of Waste Cooking Oil into Biodiesel. EKSAKTA [Internet]. 2024Nov.8 [cited 2024Nov.15];25(04):412-23. Available from: https://eksakta.ppj.unp.ac.id/index.php/eksakta/article/view/545

References

  1. Khan N, Maseet M, Basir SF. (2020). Synthesis and characterization of biodiesel from waste cooking oil by lipase immobilized on genipin cross-linked chitosan beads: A green approach. Int J Green Energy. 17(1):84–93.
  2. Ghosh N, Halder G. (2022). Current progress and perspective of heterogeneous nanocatalytic transesterification towards biodiesel production from edible and inedible feedstock: A review. Energy Convers Manag. 270(7):116292.
  3. Aboudi Mana SC, Hanafiah MM, Chowdhury. (2017). Environmental characteristics of clay and clay-based minerals. Geol Ecol Landscapes. 1(3):155–61.
  4. Adu-Gyamfi MN, Raj A, Golding P, Perez L, Golding D, Contreras LR, et al. (2022). Moving towards renewable energy to mitigate carbon emissions from fossil fuel. Am J Environ Sci Eng. 6(2):91–100.
  5. Bargole SS, Singh PK, George S, Saharan VK. (2021). Valorisation of low fatty acid content waste cooking oil into biodiesel through transesterification using a basic heterogeneous calcium-based catalyst. Biomass and Bioenergy. 146(2):105984.
  6. Yuvenda D, Sudarmanta B, Jamaludin, Muraza O, Putra RP, Lapisa R, Zainul R et al. (2022). Combustion and Emission Characteristics of CNG-Diesel Dual Fuel Engine with Variation of Air Fuel Ratio. Automot Exp. 5(3):507–27.
  7. Negm NA, Rabie AM, Mohammed EA. (2018). Molecular interaction of heterogeneous catalyst in catalytic cracking process of vegetable oils: chromatographic and biofuel performance investigation. Appl Catal B Environ. 239:36–45.
  8. Chang A, Pan J-H, Lai N-C, Tsai M-C, Mochizuki T, Toba M, et al. (2020). Efficient simultaneous esterification/transesterification of non-edible Jatropha oil for biodiesel fuel production by template-free synthesized nanoporous titanosilicates. Catalyst Today 356(10):56–63.
  9. Salmasi MZ, Kazemeini M, Sadjadi S. (2020). Transesterification of sunflower oil to biodiesel fuel utilizing a novel K2CO3/Talc catalyst: Process optimizations and kinetics investigations. Ind Crops Prod. 156(8):112846.
  10. Topare NS, Patil KD. (2021). Biodiesel from waste cooking soybean oil under ultrasonication as an alternative fuel for diesel engine. Material Today. 43:510–3. 8
  11. Mohadesi M, Aghel B, Gouran A, Razmehgir MH. (2022). Transesterification of waste cooking oil using Clay/CaO as a solid base catalyst. Energy. 242
  12. Kumar S, Deswal V. (2022). Optimization at low temperature transesterification biodiesel production from soybean oil methanolysis via response surface methodology. Energy Sources, Part A Recover Util Environ Eff. 31;44(1):2284–93.
  13. Salmasi MZ, Kazemeini M, Sadjadi S. (2020). Transesterification of sunflower oil to biodiesel fuel utilizing a novel K2CO3/Talc catalyst: Process optimizations and kinetics investigations. Ind Crops Prod. 156(8)
  14. Altalhi AA, Mohamed EA, Morsy SM, Abou Kana MTH, Negm NA. (2021). Catalytic manufacture and characteristic valuation of biodiesel-biojet achieved from Jatropha curcas and waste cooking oils over chemically modified montmorillonite clay. J Mol Liq. 340
  15. Đặng TH, Nguyễn XH, Chou CL, Chen BH. (2021). Preparation of cancrinite-type zeolite from diatomaceous earth as transesterification catalysts for biodiesel production. Renew Energy. 174:347–58.
  16. Febiola F, Rahmayeni, Admi, Syukri. (2023). Kaolinite and Illite Based Clay Supporting Nickel: Its Synthesis, Characterization, and Catalytic Optimazion in a Lab-Scale Fatty Acid Methyl Ester Production. Her Bauman Moscow State Tech Univ Ser Nat Sci. 109(4):159–74.
  17. Syukri, Islami DM, Saputra Y, Seprianti S, Wahyuni S, Ramadhani F, Arief S, et al. (2019). Natural Zeolits and Its Modifications with Protons and Copper As the Catalyst for Esterification of Ethanol with Acetic Acid. KnE Eng. 1(2):296.
  18. Abukhadra MR, Mostafa M, El-Sherbeeny AM, Ahmed Soliman AT, Abd Elgawad AEE. (2020). Effective transformation of waste sunflower oil into biodiesel over novel K+ trapped clay nanotubes (K+/KNTs) as a heterogeneous catalyst; response surface studies. Microporous Mesoporous. 306(5)
  19. Syukri S, Septioga K, Arief S, Putri YE, Efdi M, Septiani U. (2020). Natural Clay of Pasaman Barat Enriched by CaO of Chicken Eggshells as Catalyst for Biodiesel Production. Bull Chem React Eng Catalyst. 15(3):662–73.
  20. Rahmani Vahid B, Haghighi M, Alaei S, Toghiani J. (2017). Reusability enhancement of combustion synthesized MgO/MgAl2O4 nanocatalyst in biodiesel production by glow discharge plasma treatment. Energy Convers Manage. 143:23–32.
  21. Abukhadra MR, Sayed MA. (2018). K+ trapped kaolinite (Kaol/K+) as low cost and eco-friendly basic heterogeneous catalyst in the transesterification of commercial waste cooking oil into biodiesel. Energy Convers Manage. 177(9):468–76.
  22. Ali B, Yusup S, Quitain AT, Alnarabiji MS, Kamil RNM, Kida T. (2018). Synthesis of novel graphene oxide/bentonite bi-functional heterogeneous catalyst for one-pot esterification and transesterification reactions. Energy Convers Manage. 171:1–12.
  23. Alqahtani MD, Nasser N, Bin Jumah MN, AlZahrani SA, Allam AA, Abukhadra MR, et al. (2023). Insight into the Morphological Properties of Nano-Kaolinite (Nanoscrolls and Nanosheets) on Its Qualification as Delivery Structure of Oxaliplatin: Loading, Release, and Kinetic Studies. Molecules. 28(13).
  24. Rahayu, Nengsih, Z. W., Arief, S., Rilda, Y., Alif, M. F., & Syukri. (2024). Separation of Kaolinite from Clay Minerals and Its Catalytic Activity in Transesterification Reactions. Hydrogen Jurnal Kependidikan Kimia. 12(2), 16–25.
  25. Abukhadra MR, Mohamed AS, El-Sherbeeny AM, Soliman ATA. (2020). Enhanced Adsorption of Toxic and Biologically Active Levofloxacin Residuals from Wastewater Using Clay Nanotubes as a Novel Fixed Bed: Column Performance and Optimization. ACS Omega. 5(40):195–205.
  26. Xu H, Fan E, Liu J, Sun S, Shao G, Wang H, et al. (2019). Thermal stability and E. coli adsorption of kaolinite nanotubes. Appl Clay Sci. 181(100)
  27. Abukhadra MR, Bakry BM, Adlii A, Yakout SM, El-Zaidy MA. (2019). Facile conversion of kaolinite into clay nanotubes (KNTs) of enhanced adsorption properties for toxic heavy metals (Zn2+, Cd2+, Pb2+, and Cr6+) from water. J Hazard Mater. 374(1):296–308.
  28. Li X, Wang D, Liu Q, Komarneni S. (2019). A comparative study of synthetic tubular kaolinite nanoscrolls and natural halloysite nanotubes. Appl Clay Sci. 168 (42) : 1–7.
  29. Li Y, Liu Q, Li J, Hou D, Zhang J, Li J. (2022). The preparation of high-yield uniform nanotubes from coal-measure kaolinite. Appl Clay Sci. 229(8)
  30. Cai X, Li C, Tang Q, Zhen B, Xie X, Zhu W, et al. (2019). Assembling kaolinite nanotube at water/oil interface for enhancing Pickering emulsion stability. Appl Clay Sci 172(1):115–22.
  31. Mohd Johari, S. A., Ahmad Farid, M. A., Ayoub, M., Rashidi, N. A., & Andou, Y. (2024). Optimization and kinetic studies for biodiesel production from dairy waste scum oil via microwave assisted transesterification. Environmental Technology & Innovation. 34