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Submitted
Feb 23, 2024
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May 23, 2024
Published
Jun 30, 2024
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Abstract

Conductive polymer composites were synthesized using a crosslinking method, enhancing conductivity through the incorporation of carbon additives. Non-conductive natural polymers, corn starch, and natural rubber were blended with carboxymethyl cellulose (CMC) as a crosslinking agent, enhancing polymer bonding. CMC also served as a compatibilizer, improving corn starch properties. Glycerol acted as a plasticizer, enhancing flexibility and processability. Addition of carbon nanotube (CNT), graphite, and carbon foam yielded low-density materials, with carbon foam providing optimal porosity. The crystalline properties mirrored the added conductive carbon, while the chemical structure remained unchanged. At 0.1 Hz, electrical conductivity varied: 1.192 x 10-7 S.cm-1 (no carbon), 6.123 x 10-4 S.cm-1 (CNT), 7.656 x 10-4 S.cm-1 (graphite), and 3.134 x 10-2 S.cm-1 (carbon foam). Graphite incorporation demonstrated an electrical conductivity of 7.838 x 10-4 S.cm-1. The introduced carbon additives facilitated a conductive pathway in corn starch-based polymer composites, elevating material conductivity.

Keywords

Conductive polymer composites Carbon additives Crosslinking method Electrical conductivity

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How to Cite
1.
Fiqri M, Humaidi S, Frida E, Estananto E. Exploring Synergies: Tailoring Electrical Conductivity in Novel Corn Starch and Natural Rubber Polymer Composites through Varied Carbon Additives. EKSAKTA [Internet]. 2024Jun.30 [cited 2024Jul.27];25(02):188-200. Available from: https://eksakta.ppj.unp.ac.id/index.php/eksakta/article/view/500

References

  1. Idumah C I. (2021). Novel trends in conductive polymeric nanocomposites, and bionanocomposites. Synthetic Metals, 273 116674.
  2. Peng S, Yu Y, Wu S and Wang C-H. (2021). Conductive Polymer Nanocomposites for Stretchable Electronics: Material Selection, Design, and Applications. ACS Applied Materials & Interfaces, 13 43831–54.
  3. Rashid A Bin and Hoque M E. (2022). Polymer nanocomposites for defense applications. Advanced Polymer Nanocomposites (Elsevier) pp 373–414
  4. Biglari N and Zare E N. (2024). Conjugated polymer-based composite scaffolds for tissue engineering and regenerative medicine. Alexandria Engineering Journal, 87 277–99.
  5. Kanoun O, Bouhamed A, Ramalingame R, Bautista-Quijano J R, Rajendran D and Al-Hamry A. (2021). Review on Conductive Polymer/CNTs Nanocomposites Based Flexible and Stretchable Strain and Pressure Sensors. Sensors, 21 1–29.
  6. Schmitz D P, Santana L, Barra G M O and Soares B G. (2024). 3D printed honeycomb bilayer structures based on polylactic acid as lightweight microwave absorbing materials. Polymers for Advanced Technologies, 35
  7. Zheng S, Wang Y, Zhu Y and Zheng C. (2024). Recent advances in structural design of conductive polymer composites for electromagnetic interference shielding. Polymer Composites, 45 43–76.
  8. Zhou Y, Burgoyne Morris G H and Nair M. (2024). Current and emerging strategies for biocompatible materials for implantable electronics. Cell Reports Physical Science, 101852.
  9. Estananto E, Bonardo D, Suyatman S and Nuruddin A. (2024). The Influence of 2-Methoxyethanol as Capping Agent on WO 3 -Based Carbon Monoxide Gas Sensor Characteristics. Journal of Physics: Conference Series, 2705 012017.
  10. Huang Y, Kormakov S, He X, Gao X, Zheng X, Liu Y, Sun J and Wu D. (2019). Conductive Polymer Composites from Renewable Resources: An Overview of Preparation, Properties, and Applications. Polymers, 11
  11. Sharma S, Sudhakara P, Omran A A B, Singh J and Ilyas R A. (2021). Recent Trends and Developments in Conducting Polymer Nanocomposites for Multifunctional Applications. Polymers, 13 2898.
  12. Lux F. (1993). Models proposed to explain the electrical conductivity of mixtures made of conductive and insulating materials. Journal of Materials Science, 28 285–301.
  13. Xu H, Cheng H, McClements D J, Chen L, Long J and Jin Z. (2022). Enhancing the physicochemical properties and functional performance of starch-based films using inorganic carbon materials: A review. Carbohydrate Polymers, 295 119743.
  14. Dua S, Arora N, B. G. P, Saxena R C, Ganguly S K and T. S. (2024). Conjugated polymer-based composites for anti-corrosion applications. Progress in Organic Coatings, 188 108231.
  15. Wang Y and Feng W. (2022). Introduction of Conductive Polymers. Conductive Polymers and Their Composites (Singapore: Springer Nature Singapore) pp 1–31
  16. Sumdani M G, Islam M R, Yahaya A N A and Safie S I. (2022). Recent advancements in synthesis, properties, and applications of conductive polymers for electrochemical energy storage devices: A review. Polymer Engineering & Science, 62 269–303.
  17. Amin M R, Chowdhury M A and Kowser M A. (2019). Characterization and performance analysis of composite bioplastics synthesized using titanium dioxide nanoparticles with corn starch. Heliyon, 5
  18. Yemata T A, Ye Q, Zhou H, Kyaw A K K, Chin W S and Xu J. (2017). Conducting polymer-based thermoelectric composites: Principles, processing, and applications (Elsevier Ltd)
  19. Wu Y, Wang Z, Liu X, Shen X, Zheng Q, Xue Q and Kim J K. (2017). Ultralight Graphene Foam/Conductive Polymer Composites for Exceptional Electromagnetic Interference Shielding. ACS Applied Materials and Interfaces, 9 9059–69.
  20. Chatterjee S, Mahmood S, Hilles A R, Thomas S, Roy S, Provaznik V, Romero E L and Ghosal K. (2023). Cationic starch: A functionalized polysaccharide based polymer for advancement of drug delivery and health care system - A review. International Journal of Biological Macromolecules, 248 125757.
  21. Leksawasdi N, Chaiyaso T, Rachtanapun P, Thanakkasaranee S, Jantrawut P, Ruksiriwanich W, Seesuriyachan P, Phimolsiripol Y, Techapun C, Sommano S R, Ougizawa T and Jantanasakulwong K. (2021). Corn starch reactive blending with latex from natural rubber using Na+ ions augmented carboxymethyl cellulose as a crosslinking agent. Scientific Reports, 11 1–10.
  22. Kwon Y-J, Park J-B, Jeon Y-P, Hong J-Y, Park H-S and Lee J-U. (2021). A Review of Polymer Composites Based on Carbon Fillers for Thermal Management Applications: Design, Preparation, and Properties. Polymers, 13 1312.
  23. B.A P, N L, Buradi A, N S, B L P and R V. (2022). A comprehensive review of emerging additive manufacturing (3D printing technology): Methods, materials, applications, challenges, trends and future potential. Materials Today: Proceedings, 52 1309–13.
  24. Bonardo D, Septiani N L W, Estananto E, Suyatman S, Humaidi S and Yuliarto B. (2023). Synthesis and characterization of WO3 sensitive layers for NO2 gas sensor application. p 050012
  25. Agrawal P R, Kumar R, Teotia S, Kumari S, Mondal D P and Dhakate S R. (2019). Lightweight, high electrical and thermal conducting carbon-rGO composites foam for superior electromagnetic interference shielding. Composites Part B: Engineering, 160 131–9.
  26. Petit T and Puskar L. (2018). FTIR spectroscopy of nanodiamonds: Methods and interpretation. Diamond and Related Materials, 89 52–66.
  27. Estananto E, Utari L, Septiani N L W, Bonardo D, Nuruddin A, Suyatman S and Yuliarto B. (2023). Anatase TiO2 on graphene-coated cotton flexible sensor at room temperature. p 050032
  28. Zhang D, Liu L, Lan X, Li F, Liu Y and Leng J. (2023). Experimental study on nonlinearity of unidirectional carbon fibre-reinforced shape memory polymer composites. Composites Part A: Applied Science and Manufacturing, 166 107372.
  29. Najmi L and Hu Z. (2023). Effects of Carbon Nanotubes on Thermal Behavior of Epoxy Resin Composites. Journal of Composites Science, 7 313.
  30. Bonardo D, Septiani N L W, Amri F, Estananto, Humaidi S, Suyatman and Yuliarto B. (2021). Review—Recent Development of WO 3 for Toxic Gas Sensors Applications . Journal of The Electrochemical Society, 168 107502.
  31. Tadesse M G, Ahmmed A S and Lübben J F. (2024). Review on Conductive Polymer Composites for Supercapacitor Applications. Journal of Composites Science, 8 53.
  32. Wang M, Tang X H, Cai J H, Wu H, Shen J Bin and Guo S Y. (2021). Construction, mechanism and prospective of conductive polymer composites with multiple interfaces for electromagnetic interference shielding: A review. Carbon, 177 377–402.
  33. Bonardo D, Darsono N, Humaidi S, Imaduddin A and Silalahi N S. (2023). Effect of calcination frequency on the thermoelectric properties of Ti doped CuCrO2 by solid state method. Journal of Metals, Materials and Minerals, 33 1785.
  34. Vandghanooni S and Eskandani M. (2019). Electrically conductive biomaterials based on natural polysaccharides: Challenges and applications in tissue engineering. International Journal of Biological Macromolecules, 141 636–62.
  35. Wang Y and Weng G J. (2018). Electrical Conductivity of Carbon Nanotube- and Graphene-Based Nanocomposites. Micromechanics and Nanomechanics of Composite Solids (Cham: Springer International Publishing) pp 123–56
  36. Kondrashov S V., Soldatov M A, Gunyaeva A G, Shashkeev K A, Komarova O A, Barinov D Y, Yurkov G Y, Shevchenko V G and Muzafarov A M. (2018). The use of noncovalently modified carbon nanotubes for preparation of hybrid polymeric composite materials with electrically conductive and lightning resistant properties. Journal of Applied Polymer Science, 135 2–9.
  37. Peidayesh H, Mosnáčková K, Špitalský Z, Heydari A, Šišková A O and Chodák I. (2021). Thermoplastic starch–based composite reinforced by conductive filler networks: Physical properties and electrical conductivity changes during cyclic deformation. Polymers, 13